K-Patents Applications in Semiconductor Industry

Semiconductor and Microelectronics Fabrication:
Wet Chemical Wafer Processing

The K-Patents Semicon Refractometer measures real-time the liquid chemical concentrations in the semiconductor fabrication process, i.e. from chemical supplies down to fab in-line and tool in-situ chemical quality control. The concentration of dissolved solids is determined by making an optical measurement of the solution’s refractive index. The advantage of this principle is that the same instrument can be used to measure any chemical.

The K-Patents Refractometer provides a continuous 4-20 mA or Ethernet signal and immediate feedback to the control system, if the chemical is out of the specifications. The K-Patents Refractometer is physically small and easy to install in the bulk chemicals dispense, and in point of use chemical blending, spiking and monitoring applications.

Ref. Application Note 5.00.00 pdf


Bulk Chemical Delivery Systems

Fabs with many products typically use a high number of different bulk chemicals. And since the predominant delivery method of chemicals in Fabs is by drum, every time a person handles a new drum there is a potential for human error. Occasionally, wafer defects occur due to wrong drum of chemical being dispensed onto the wafers. Therefore, the type of chemical should always be monitored and validated before it enters the process.

With K-Patents technology, low and high concentration alarms can be configured to eliminate these defects caused by human errors in container handling or equipment failure at the distribution point.

Ref. Application Note 5.00.10 pdf
Ref. Paper: In-Situ Chemical Monitoring in Semiconductor Fabrication Chemical Supplies pdf


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Anisotropic Etch of Silicon

Wet etch is used to chemically remove layers (metal, silicon, photoresist) from the surface of a wafer. For instance, potassium hydroxide (KOH) is commonly used for etching Silicon. The etch rate of silicon in a KOH bath depends on the bath temperature and the KOH concentration. As etching progresses some KOH (namely OH- ions) is consumed in the process. K-Patents Semicon Refractometer provides a real-time indication of the KOH concentration and helps to determine the correct etch end point. This way the bathlife can be increased. In some cases the bathlife can be doubled.

Ref. Application Note 5.00.20 pdf

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Post-Etch Wafer Cleaning:
EKC in Spray Solvent Tools

K-Patents Semicon Refractometer is used for concentration measurement of aqueous mixtures, such as EKC-265. EKC-265 is formulated to remove etching residues namely the remaining polymer material after the etching and the ashing operation (where the photoresist layer is removed). The purpose of the real-time in situ measurement is to determine the bath life. The water content of the rinsing bath starts from 18% and goes down to 13% where it stabilizes. The more water, the more aggressive the solution is. The refractometer provides a reliable indication of the bathlife, so that the bathlife can be extended, the wafer throughput can be increased and the overall chemical consumption can be reduced.

Ref. Application Note 5.00.30 pdf

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Chemical Mechanical Planarization (CMP): Blending and Dispense of Hydrogen Peroxide H2O2 Slurry

The CMP slurries, especially oxide polishing slurries commonly require mixing or dilution before use. It is essential to measure the H2O2 concentration in the mixed slurry, because altering the concentration of the slurry constituents will affect the chemical reaction rates and wafer polishing rate. Too much H2O2 can result in contamination of the wafer. K-Patents Semicon Refractometer is an in-line metrology device, which measures the H2O2 content of the slurry during blending and in the slurry dispense line. K-Patents measurement signal is not influenced by the entrapped air.

Ref. Application Note 5.00.50 pdf


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To find out how You can benefit from using a K-Patents Process Refractometer, please contact us or send us an Information request.